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CATALYSIS OVERVIEW

 

AMBERLYST™ polymer based catalysis involves mostly the use of functionalized styrene divinylbenzene copolymers with different surface properties and porosities. They are supplied as spherical polymers in the gel or macroreticular form. They have been used for 40 years in a variety of reactions.

 

Besides their catalytic performance, Amberlyst™ polymer catalysts are easy to handle and show a low degree of corrosivity. They are the catalysts of choice for some large markets such as fuel ethers, and bisphenol A. Alternatively these catalysts can be doped with various metals to enhance their catalytic properties. Today more and more neutral adsorbents with extended surface properties are used as carriers for biocatalysts and metal complexes.

 

AMBERLYST catalysts are available in a wide range of particle sizes (from 0.3 mm to 1.2 mm) which have been optimized for their end use to allow good selectivity, low pressure drop and lowest cost operations.

Our major building blocks for Amberlyst catalysts are polystyrene based copolymers but acrylic and phenolic backbones are also available. If you are looking for a specific polymer or functional group on a polymeric catalyst please feel free to contact us. We are interested in working with you.

 

 

 

List of Reactions and Recommended Polymeric General Catalysts

 

 

Reaction
Reaction Product
Amberlyst™ Catalysts
Aldolization

Diacetone alcohol and other Aldols

A26 OH
Alkylation

Alkylphenols

15Dry, 35Dry, 36Dry
Condensation

Bisphenol A

Phenol (Condensation of Carbonyl and furan impurities)

31Wet, 121Wet, 131Wet, 232Wet

16Wet, 36Wet

Dimerization

Iso-octene and Iso-Octane

35Wet, 36Wet
Esterification

Acrylates (EA, BA, 2-EHA, MMA)
Acetates (MA, EA, BA, PA)
Fatty Acid esters

16Wet, 131Wet, 39Wet, 46

15Wet, 16Wet, 36Wet, 131Wet

15Wet, 36Wet, 70

Etherification

Fuel ethers (MTBE, ETBE, TAME)

15Wet, 35Wet, CH10
Hydrogenation

MIBK

TAME

CH28,

CH10

Hydration Alcohols from light olefins 15Wet, 70

 

 

 

For sampling, pricing and availability of AMBERLYST™ catalysts please contact your Rohm and Haas sales representative.

 

 

Further Reading

  • Irving M. Abrams, John R. Millar, "A history of the origin and development of macroporous ion-exchange resins", Reactive & Functional Polymers 35 (1997) 7-22

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